1. Electronic configuration of a transition element X in +2 oxidation state is [Ar]3d5. What is the atomic number
Explanation:To determine complete electronic configuration of an element, we must know the electronic configuraiton of nearest noble gas electronic configuration, whose atomic number increase as follow: 2(He),10(Ne),18(Ar),36(Kr),54(Xe),86(Rn),118(Og). A transition element X is in +2 oxidation state, it means it has two electrons less then its neutral atom. So, simply add this oxidation state to the electronic configuration in order to calculate total mumber of electrons. Total number of elecrons are 18 (Ar) +5 (3d) + 2 = 25. As number of electrons are equal to number proton in a neutral atom, so its number of protons (or atom number) is 25.
2. Whic of the following metal hydroxide is least soluble in water
Explanation: As solubility of only hydroxides of second group elements increases down the group. Mg(OH)2 is the least soluble as Mg is on the top in IIA group among these elements.
3. The abnormal enlargment of thyroid gland is due to deficiency of -------- in diet.
Explanation: Iodine is required by thyroid gland for production of the thyroid harmone which regulate the metabolism. A human body is unable to synthesize the iodine,therefore, it is an essential and taken in diet. Its deficieny in diet can lead to abnormal enlargment of thyroid gland (also known as goiter) which tries to make up shortage by growing larger.
4. Nucleic acids are repeating units of
Explanation:Nucleotides are made up of ribose or deoxyribose sugar attached to phoshphate group and nitrogeneous bases. Nucleotides are repeating units of nucleic acids. Nucleosides are subunit of nucleic acid comprising of a molecule of sugar linked to a nitrogen containing base.
5. Polyethylene is an example of
Explanation: Monomer of polyethylene is ethene molecule. The pi bond of ethene are broken down homolytically and are used to bind next monomer via sigma bonds to form a macromolecule. This kind of polymers is called addition polymer.
6. Which of the following alloy is used in prepartion of Raney Nickle?
Explanation: Raney Nickle is spongy form of Nickle with porous surface. The Raney nickle is produced from reaction of Ni-Al alloy with sodium hydroxide.
7. A mixture consists of 40% (+) tartaric acid and 60% (-) tartaric acid. The mixture rotates plane polarized light
Explanation: (+) tartaric acid is dextro rotatory as it rotates plane polarized light in clockwise direction and (-) tartaric acid is levorotatory as it rotates plane polarized light in anti-clockwise direction. A racimic mixture (50%:50%) of (+) and (-) forms is optically inactive. However, if mixture contains one optical isomer in excess, then mixture is optical active and it will rotate plane polarized lighth according to isomer present in excess (anti-clockwise in above case).
8. Which of the following is correct?
Explanation:SN2 and E2 are one step reactions. Both reactions are bimolecular nucleophilic and elimination reactions, respectively. SN2 involves attack of nucleophile while E2 involves attack of base on hydrogen and complete in one step.
9. Hydrogen bonding is maximum in
Explanation: For hydrogen bonding, hydrogen atom should be bonded with highly electronegartive atoms such F, O, N etc. Ethanol contains hydrogen atom directly bonded to highly electronegative O atom, while rest of the compounds donot contain. So hydrogen bonding is only present in ethanol.
10. Acetic acid reacts with Na metal to form
Explanation: Sodium (Na) metal has strong reducing power and can reduce acidic proton of an acid to hydrogen gas along with formation of sodium salt of that acid.
11. Which region of electromanetic radiation is used in IR spectroscopy
Explanation: Ordinary region of IR electromanetic radiations lies between 2.5µm-16µm.
12. The hard and rocky earth crust is called
Explanation: Atmospher contains layers of gases which surround the earth. Hydrosphere contains all water bodies i.e., ocean, rivers, stream, lakes, glacier etc. Lithosphere contains hard and rigid rocky earth crust. Biosphere contains the regeion which supports the life i.e., air, lakes etc.
13. Which of the following elements form alloys
Explanation: Alloys are mixture of two or more than two metals. Transition elements have ability to make the alloys because these elements have atoms of similar atomic size wich can take easily the position of crystal lattice of any other transition element.
14. Which of the following pairs has both member from same period of the periodic table?
Explanation: Both Na and Cl are present in third period of the periodic table.
15. Carbon atom in formaldehyde is
Explanation: Formaldehyde has only single carbon atom that is bonded to a oxygen atom and two hydrogen atoms. Its bond angle is 120° and geometry is trigonal planer, that is only possibe with sp2 carbon atom.
16. R-CN gives---------------when reacted with LiAlH4
Explanation: Alkyl nitriles give primary amine throgh conversion of CN to CH2-NH2.
17. Pyridine is
Explanation: Pyridine has cyclic, planer and 6 pi electrons, so it is a aromatic. It also contains one hetro atom in the cyclic ring, so it is hetrocyclic compound.
Nice Q...thanku
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